Thermodynamics: JEE Main 2023 Physics question

$\left(P+\frac{a}{V^{2}}\right)(V-b)=R T$ represents the equation of state of some gases. Where $P$ is the pressure, $V$ is the volume, $T$ is the temperature and $a, b, R$ are the constants. The physical quantity, which has dimensional formula as that of $\frac{b^{2}}{a}$, will be: