JEE Main 202628 Jan, Morning shiftChemistryEasyOrganic Compounds Containing Nitrogen35× since 2005Consider the following reactions giving major product. Identify the correct reaction.AOption A. Benzylamine (C6H5CH2NH2\mathrm{C_6H_5CH_2NH_2}C6H5CH2NH2) →CHCl3/KOH, Δ\xrightarrow{\mathrm{CHCl_3/KOH},\ \Delta}CHCl3/KOH, Δ C6H5CH2N+≡C−\mathrm{C_6H_5CH_2N^+{\equiv}C^-}C6H5CH2N+≡C− →(i) Sn/HCl/Δ (ii) pH adjusted\xrightarrow{\text{(i) Sn/HCl}/\Delta\text{ (ii) pH adjusted}}(i) Sn/HCl/Δ (ii) pH adjusted C6H5CH2NH2\mathrm{C_6H_5CH_2NH_2}C6H5CH2NH2BOption B. H3CCH2−CO−NH2+Br2+4KOH (alc)→ΔH3CCH2NH2+2KBr+K2CO3+2H2O\mathrm{H_3CCH_2{-}CO{-}NH_2+Br_2+4KOH\,(alc)}\xrightarrow{\Delta}\mathrm{H_3CCH_2NH_2+2KBr+K_2CO_3+2H_2O}H3CCH2−CO−NH2+Br2+4KOH(alc)ΔH3CCH2NH2+2KBr+K2CO3+2H2OCOption C. C6H5−NH−CO−C6H5→HNO3:H2SO4 (1:2)\mathrm{C_6H_5{-}NH{-}CO{-}C_6H_5}\xrightarrow{\mathrm{HNO_3:H_2SO_4}\ (1:2)}C6H5−NH−CO−C6H5HNO3:H2SO4 (1:2) product with NO2\mathrm{NO_2}NO2 on the benzoyl ring (meta to C=O)DOption D. Potassium phthalimide + C6H5−X\mathrm{C_6H_5{-}X}C6H5−X →(i) Heat (ii) Hydrolysis\xrightarrow{\text{(i) Heat (ii) Hydrolysis}}(i) Heat (ii) Hydrolysis C6H5NH2\mathrm{C_6H_5NH_2}C6H5NH2CheckStep-by-step hintSkip · show solution
